ESR and optical absorption spectra of reduced vanadium ions in Ca2NaMg2V3O12 garnet
نویسنده
چکیده
Optical absorption and ESR spectra of reduced vanadium centres in Ca2NaMg2VjOlz are reported. The spectra are interpreted as arising from tetrahedrally coordinated V" and octahedrally coordinated V". The ESR and optical data are correlated using molecular orbital (MO) theory. The composition of the flux-grown single crystals is analysed and discussed.
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